Stereoselective Reduction of α-Cyclopropyl Ketones and α-Cyclopropyl Aldols. Stereo-directing Effect by α-Trimethylsilyl Group

DOI: 10.1016/S0040-4039(01)80590-6

Source and publish data:

Tetrahedron Letters p. 5447 - 5450 (1989)

Update date:2022-07-31

Topics: -Reduction

Authors:

Shimazaki, Masato

Hara, Hisaaki

Suzuki, Keisuke

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80590-6

Stereoselective reduction of α-chiral α-cyclopropyl ketones and α-cyclopropyl aldols is described.Introduction of trimethylsilyl (TMS) group to the α-position of cyclopropyls leads to virtually complete stereoselection to give the stereo-defined β-cyclopr

Full text of DOI:10.1016/S0040-4039(01)80590-6

Products guided by the article

Product name:(3R,4R)-3-Methyl-2-trimethylsilanyl-dodec-1-en-4-ol

Cas No:127583-01-1

R&D Labs maybe for 127583-01-1

Hangzhou utanpharma Co., Ltd

Contact:86-571-87758773

Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
Hangzhou Zyter Biological & Chemical Technology Co., Ltd.

website:http://www.zyterpharm.com

Contact:+86-18858184290

Address:West Wenyi Road, Cangqian, Yuhang
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town

Relevant to this article

Doi:10.1021/ja01343a057
(1932)
(Naphthalen-1-yloxy)-acetic acid benzylidene/(1-phenylethylidene)-hydrazide derivatives: Synthesis, antimicrobial evaluation, and QSAR studies

Doi:10.1007/s00044-011-9776-0
(2012)
Beta-adrenergic blocking agents. IV. Variation of the 2-naphthyl group of pronethalol (2-isopropylamino-1-(2-naphthyl)ethanol).

Doi:10.1021/jm00303a027
(1969)
Self-Assembly of Disorazole C₁ through a One-Pot Alkyne Metathesis Homodimerization Strategy

Doi:10.1002/anie.201501922
(2015)
STERIC EFFECTS OF PHOSPHINE LIGANDS ON THE PHOTOCHEMISTRY PF Mn2(CO)10

Doi:10.1016/0022-328X(83)80199-5
(1983)
Spectroscopic and TD-DFT studies on the turn-off fluorescent chemosensor based on anthraldehyde N(4) cyclohexyl thiosemicarbazone for the selective recognition of fluoride and copper ions

Doi:10.1016/j.poly.2016.01.021
(2016)

Article Doi