127583-42-0

Basic information

• Product Name: 2-Propanone, 1-[(4-methylphenyl)sulfinyl]-, (S)-
• CAS NO: 127583-42-0
• Molecular Formula: C10H12O2S
• Molecular Weight: 196.27
• Mol File: 127583-42-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propanone, 1-[(4-methylphenyl)sulfinyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-[(4-methylphenyl)sulfinyl]-, (S)-(127583-42-0)
• EPA Substance Registry System: 2-Propanone, 1-[(4-methylphenyl)sulfinyl]-, (S)-(127583-42-0)

Safety Data

• Hazardous Substances Data: 127583-42-0(Hazardous Substances Data)

Upstream product

• 83859-12-5 N,N-Dimethyl-N'-[1-methyl-2-((R)-toluene-4-sulfinyl)-eth-(E)-ylidene]-hydrazine 
• 56742-98-4 1-<(4-methylphenyl)sulphinyl>propan-2-one 
• 1200-13-1 1-(p-tolylsulfanyl)propan-2-one 

Downstream Products

• 1293384-86-7 (+)-(sR,3S,4S)-5-oxo-3-phenyl-4-(p-tolylsulfinyl)hexanal 
• 218168-33-3 (4R,6R)-4-Benzyloxymethyl-2,2-dimethyl-6-((S)-toluene-4-sulfinylmethyl)-[1,3]dioxane 
• 218168-24-2 (R)-1-Benzyloxy-4-hydroxy-5-((S)-toluene-4-sulfinyl)-pentan-2-one 
• 218168-26-4 (2R,4R)-1-Benzyloxy-5-((S)-toluene-4-sulfinyl)-pentane-2,4-diol 
• 218168-21-9 (Z)-5-Benzyloxy-4-hydroxy-1-((S)-toluene-4-sulfinyl)-pent-3-en-2-one 
• 127583-47-5 7-chloro-1-(p-tolylsulfinyl)-5-hepten-2-one 
• 157660-33-8 (Rs)-3-endo-methyl-3-exo-(p-tolylsulfinyl)methyl-2,4-dioxa-cis-bicyclo<3.3.0>octane 
• 157611-55-7 (Rs)-3-exo-methyl-3-endo-(p-tolylsulfinyl)methyl-2,4-dioxa-cis-bicyclo<3.3.0>octane 

Relevant articles and documents

Highly enantiomeric purity conversion of α-sulfinyl oximes and α-sulfinyl hydrazones to the corresponding β-keto sulfoxides with butyltriphenylphosphonium periodate (BUTPPPI)

Butyltriphenylphosphonium periodate (Ph3P+BuIO 4-)1 is readily prepared as a white solid from butyltriphenylphosphonium chloride, performs conversion of α-sulfinyl oximes (2) and α-sulfinyl hydrazones (4) to the

Enantioselective oxidation of sulphides to sulphoxides in the presence of bovine serum albumin

In situ generated dioxiranes oxidize a series of prochiral sulphides to the corresponding sulphoxides with enantiomeric excess (e.e.) up to 89%, when bovine serum albumin (BSA) is used as chiral auxiliary. The degree of enantioselectivity, as well as yield and reaction times, depend upon the nature of the dioxirane. These are compared with enantioselectivities attainable for the same transformations by using peroxomonosulfate alone, i.e. in the absence of ketone. In the oxidation of prochiral keto sulphides (wherein the carbonyl functionality serves as precursor of dioxirane) with peroxomonosulfate, optically active keto sulphoxides are isolated in satisfactory chemical and optical yield (up to e.e. 84%).