127597-98-2

Upstream product

• 75-11-6 diiodomethane 
• 127597-94-8 (3S)-4-Phenyl-3-(N-(p-toluenesulfonyl)amino)-2-butanone 

Downstream Products

• 127642-92-6 anti-2-methyl-3-(N-tosylamino)-4-phenyl-1-butanol 
• 127642-91-5 syn-2-methyl-3-(N-tosylamino)-4-phenyl-1-butanol 
• 131544-35-9 syn-2-methyl-3-(benzyltosylamino)-4-phenyl-1-butanol 
• 131544-40-6 anti-2-methyl-3-(benzyltosylamino)-4-phenyl-1-butanol 
• 131544-29-1 2-methyl-3-(benzyltosylamino)-4-phenyl-1-butene 

Relevant academic research and scientific papers

Manipulation of Substrate-Controlled Diastereoselectivities in Hydroborations in Acyclic Allylamine Derivatives

Racemic, and optically active, 2-methyl-3-(N-tosylamino)alkenes I were prepared and subjected to both catalyzed and uncatalyzed hydroborations.Data obtained for the catalyzed hydroborations of these allylamine derivatives are consistent with the theory of

SUBSTRATE-CONTROLLED DIASTEREOSELECTIVITY IN CATALYZED AND UNCATALYZED HYDROBORATIONS OF ALLYLIC AMINE DERIVATIVES

Hydroboration of the protected, homochiral allylic amines (6)-(10) with 9-BBN, and with catecholborane/rhodium catalyst, give different stereoselectivities; the catalyzed reactions provide access to syn-3-amino-2-methyl alcohols (11)-(15).