Manipulation of Substrate-Controlled Diastereoselectivities in Hydroborations in Acyclic Allylamine Derivatives

Article abstract of DOI:10.1021/jo00003a024

Racemic, and optically active, 2-methyl-3-(N-tosylamino)alkenes I were prepared and subjected to both catalyzed and uncatalyzed hydroborations.Data obtained for the catalyzed hydroborations of these allylamine derivatives are consistent with the theory of