127598-03-2

Upstream product

• 127621-25-4 1-(benzyloxy)-3-methyl-2-(N-tosylamino)-3-butene 
• 15681-48-8 lithium dimethylcuprate 
• 115344-31-5 [(2S,3S)-3-Benzyloxymethyl-1-(toluene-4-sulfonyl)-aziridin-2-yl]-methanol 
• 115344-31-5 [(2R,3S)-3-Benzyloxymethyl-1-(toluene-4-sulfonyl)-aziridin-2-yl]-methanol 
• 127597-97-1 N-((S)-1-Benzyloxymethyl-2-oxo-propyl)-4-methyl-benzenesulfonamide 
• 131544-39-3 3-methyl-2-(N-tosylamino)-3-buten-1-ol 
• 100-39-0 benzyl bromide 

Relevant academic research and scientific papers

Regioselective nucleophilic ring opening of 2,3-aziridino alcohols

Nucleophilic ring-opening of trans and cis aziridino alcohols 1 (1') and 2 (2') by hydride- and by methyl-transfer reagents has been studied. In general, good to excellent C-2 selectivity was observed (the regioselectivity being better for the trans isome

Manipulation of Substrate-Controlled Diastereoselectivities in Hydroborations in Acyclic Allylamine Derivatives

Racemic, and optically active, 2-methyl-3-(N-tosylamino)alkenes I were prepared and subjected to both catalyzed and uncatalyzed hydroborations.Data obtained for the catalyzed hydroborations of these allylamine derivatives are consistent with the theory of

SUBSTRATE-CONTROLLED DIASTEREOSELECTIVITY IN CATALYZED AND UNCATALYZED HYDROBORATIONS OF ALLYLIC AMINE DERIVATIVES

Hydroboration of the protected, homochiral allylic amines (6)-(10) with 9-BBN, and with catecholborane/rhodium catalyst, give different stereoselectivities; the catalyzed reactions provide access to syn-3-amino-2-methyl alcohols (11)-(15).