127616-16-4Relevant academic research and scientific papers
One-pot synthesis of 5-phenylimino, 5-thieno or 5-oxo-1,2,3-dithiazoles and evaluation of their antimicrobial and antitumor activity
Konstantinova, Lidia S.,Bol'shakov, Oleg I.,Obruchnikova, Natalia V.,Laborie, Helene,Tanga, Annabelle,Sopena, Valerie,Lanneluc, Isabelle,Picot, Laurent,Sable, Sophie,Thiery, Valerie,Rakitin, Oleg A.
experimental part, p. 136 - 141 (2009/05/30)
We here report the synthesis and biological evaluation of rare 4-substituted-5-phenylimino, 5-thieno- and 5-oxo-1,2,3-dithiazoles. Dithiazoles were selectively obtained in moderate to high yields (25-73%) via a one-pot reaction from various ethanoneoximes
The reaction of acetophenone oximes with disulfur dichloride; 4-aryl-5-arylimino-1,2,3-dithiazoles and pentathiepinopyrrole
Emayan, Kumaraswamy,Rees, Charles W.
, p. 605 - 612 (2007/10/03)
Acetophenone oxime and disulfur dichloride give 5-chloro-4-phenyl-1,2,3-dithiazolium chloride 4 which on treatment in situ with primary aromatic amines gives the stable, crystalline 5-arylimino derivatives 7a-e. 4-Nitroacetophenone oxime similarly gives 5
ORGANIC HETEROCYCLOTHIAZENES. PART 19. SYNTHESIS OF 1,3,2-DITHIAZOLES USING BIS(CHLOROTHIO)NITRONIUM TETRACHLOROALUMINATE,
Gray, Michael A.,Rees, Charles W.,Williams, David J.
, p. 1827 - 1852 (2007/10/02)
Reaction of the readily prepared bis(chlorothio)nitronium tetrachloroaluminate (4) with electron-rich arylacetylenes in dichloromethane at room temperature leads to a cycloaddition reaction resulting in 4-aryl-1,2,3-dithiazolium salts (5) which when treat
