127624-06-0

Basic information

• Product Name: 4-(<1-(2-phenylethenylidene)pentyl>sulfinyl)morpholine
• CAS NO: 127624-06-0
• Molecular Weight: 305.441
• Mol File: 127624-06-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(<1-(2-phenylethenylidene)pentyl>sulfinyl)morpholine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(<1-(2-phenylethenylidene)pentyl>sulfinyl)morpholine(127624-06-0)
• EPA Substance Registry System: 4-(<1-(2-phenylethenylidene)pentyl>sulfinyl)morpholine(127624-06-0)

Safety Data

• Hazardous Substances Data: 127624-06-0(Hazardous Substances Data)

Upstream product

• 2958-89-6 N-(chlorosulfanyl)morpholine 
• 73922-80-2 1-phenylhept-2-yn-1-ol 

Relevant articles and documents

Substituted 4-(alka-1,2-dienylsulfinyl)morpholines: preparation and conversion into the corresponding sulfinic esters and alkynes by hydrolytic desulfinylation

By reaction with morpholine-4-sulfenyl chloride in the presence of triethylamine, several substituted propargylic alcohols were converted into the corresponding allenic sulfinamides 3.As a complementary method, some new allenic α-lithio sulfinamides were prepared and efficiently alkylated with organic halides.The boron trifluoride/etherate-catalyzed treatment of the allenic sulfinamides with simple saturated, allylic or propargylic alcohols provided the corresponding alka-1,2-dienesulfinic esters.Oxidation of various N,N-disubstituted allenic sulfinamides yielded the allenic sulfonamides.The acid-catalyzed hydrolysis or deuterolysis of the title sulfinamides provided the corresponding alkynes.Keywords: -sigmatropic rearrangement / α-allenic sulfinamide / organolithium derivative / α-allenic sulfinic ester / retro-ene reaction / sulfur dioxide elimination / alkyne