127635-94-3Relevant academic research and scientific papers
Toward the Development of Radiolabeled Fluorophenyl Azide-Based Photolabeling Reagents: Synthesis and Photolysis of Iodinated 4-Azidoperfluorobenzoates and 4-Azido-3,5,6-trifluorobenzoates
Cai, Sui Xiong,Glenn, Dennis J.,Keana, John F. W.
, p. 1299 - 1304 (2007/10/02)
Two approaches for the incorporation of iodine into funtionalized perfluorophenyl azides (PFPAs) were demonstrated by the synthesis of 3, 5, and 8, with the azido and iodo groups in the same aryl ring, and 14 and 15, with the azido and iodo groups in diff
4-AZIDO-2-IODO-3,5,6-TRIFLUOROPHENYLCARBONYL DERIVATIVES. A NEW CLASS OF FUNCTIONALIZED AND IODINATED PERFLUOROPHENYL AZIDE PHOTOLABELS
Cai, Sui Xiong,Keana, John F. W.
, p. 5409 - 5412 (2007/10/02)
Iodinated perfluorophenyl azide 4 and NHS ester 7 were synthesized.Photolysis of azide 4 in DEA/ cyclohexane gave N-H insertion product 9 (24percent).For photolabeling purposes, this constitutes a significant improvement over the behavior of non-fluorinat
