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Reactivite de l'allyltrimethylsilane avec les acetylcyclopropanes en presence d'acide de Lewis
Piras, P.,Afshari, M.,Leandri, G.,Monti, H.
, p. C9 - C11 (1990)
In the presence of Lewis acid, allyltrimethylsilane undergoes 1,2-addition to the carbonyl system of acetylcyclopropanes.A second direct attack of the nucleophilic reagent on the transient cyclopropylcarbynyl cation formed yields diallylic and functionalised cyclohexane derivatives.
