Reactivite de l'allyltrimethylsilane avec les acetylcyclopropanes en presence d'acide de Lewis

DOI: 10.1016/0022-328X(90)87074-N

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C11 (1990)

Update date:2022-08-15

Topics:

Authors:

Piras, P.

Afshari, M.

Leandri, G.

Monti, H.

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Article abstract of DOI:10.1016/0022-328X(90)87074-N

In the presence of Lewis acid, allyltrimethylsilane undergoes 1,2-addition to the carbonyl system of acetylcyclopropanes.A second direct attack of the nucleophilic reagent on the transient cyclopropylcarbynyl cation formed yields diallylic and functionalised cyclohexane derivatives.

Full text of DOI:10.1016/0022-328X(90)87074-N

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