127682-99-9Relevant academic research and scientific papers
DOES Me3SiCl ACTIVATE CONJUGATE ADDITION OF COPPER REAGENTS AS A LEWIS ACID ?
Horiguchi, Yoshiaki,Komatsu, Makoto,Kuwajima, Isao
, p. 7087 - 7090 (2007/10/02)
The role of Me3SiCl to accelerate conjugate addition of organocopper reagents has been examined by comparison of the stereochemical results of reactions with 6- and 2,6-disubstituted cyclohexenones, and mechanism involving an initial coordination of the chlorosilane to enones has been proposed.
