127705-80-0

Basic information

• Product Name: 1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane
• CAS NO: 127705-80-0
• Molecular Weight: 224.28
• Mol File: 127705-80-0.mol

Chemical Properties

• CAS DataBase Reference: 1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane(127705-80-0)
• EPA Substance Registry System: 1-(methoxycarbonyloxy)-1-(phenylthio)cyclopropane(127705-80-0)

Safety Data

• Hazardous Substances Data: 127705-80-0(Hazardous Substances Data)

Upstream product

• 126582-35-2 1-(phenylsulfinyl)-1-(tributylstannyl)cyclopropane 
• 79-22-1 methyl chloroformate 

Relevant articles and documents

Destannylative Pummerer-type rearrangement of 1-(tributylstannyl)-1-(phenylsulfinyl)- cyclopropane and -ethene

1-(Tributylstannyl)-1-(phenylsulfinyl)-cyclopropane and -ethene were found to react with acyl chlorides to provide the corresponding 1-acyloxy-1-(phenylthio)-cyclopropanes and -ethenes. The reaction involves the Pummerer-type rearrangement with loss of the tributylstannyl group.

Destannylative pummerer-type rearrangement of l-(phenylsulfinyl)-l-(tributylstannyl)cyclopropane

l-(Phenylsulfinyl)-l-(tributylstannyl)cyclosporane on treatment with acyl chlorides or alkyl chloroformate in refluxing dichloromethane afforded l-acyloxyl-l-phenylsulfenyl- and l-alkoxycarbonyloxy-l-phenylsulfenylcyclopropanes, respectively. The reaction