Destannylative Pummerer-type rearrangement of 1-(tributylstannyl)-1-(phenylsulfinyl)- cyclopropane and -ethene

DOI: 10.1016/S0040-4020(01)81835-4

Source and publish data:

Tetrahedron p. 6651 - 6660 (1993)

Update date:2022-08-02

Topics:

Authors:

Pohmakotr, Manat

Sithikanchanakul, Srisamorn

Khosavanna, Sujitra

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Article abstract of DOI:10.1016/S0040-4020(01)81835-4

1-(Tributylstannyl)-1-(phenylsulfinyl)-cyclopropane and -ethene were found to react with acyl chlorides to provide the corresponding 1-acyloxy-1-(phenylthio)-cyclopropanes and -ethenes. The reaction involves the Pummerer-type rearrangement with loss of the tributylstannyl group.

Full text of DOI:10.1016/S0040-4020(01)81835-4

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