127750-72-5

Upstream product

• 121587-30-2 (E)-(S)-8-Benzenesulfonyl-4,6-dimethyl-oct-4-enoic acid methyl ester 
• 13291-18-4 isopropenylmagnesium bromide 
• 299430-04-9 (S)-2-methyl-4-phenylsulfonyl-1-tetrahydropyranyloxybutane 
• 127750-71-4 (S)-6-Benzenesulfonyl-2,4-dimethyl-hex-1-en-3-ol 
• 308357-64-4 (2S)-2-methyl-4-(phenylsulfonyl)butanal 
• 121587-29-9 (3S)-3-methyl-1-phenylsulfonylbutan-4-ol 
• 127750-71-4 (3RS,4S)-2,4-Dimethyl-6-(phenylsulfonyl)hex-1-en-3-ol 
• 129423-03-6 (R)-(+)-4-(phenylsulfonyl)-2-methyl-1-butanol 
• 121587-30-2 (6S,4E)-Methyl 4,6-Dimethyl-8-(phenylsulfonyl)oct-4-enoate 

Downstream Products

• 127779-23-1 (2RS,11S,5E,9E)-5,9,11-Trimethyl-13-(phenylsulfonyl)trideca-5,9-dien-2-ol 
• 121587-32-4 (3S,12RS,4E,8E)-12-<(tert-Butyl)dimethylsilyloxy>-3,5,9-trimethyl-1-(phenylsulfonyl)trideca-4,8-diene 
• 127750-73-6 (2R,4S,6RS,8S,17RS,9E,13E)-17-<(tert-Butyl)dimethylsilyloxy>-4,8,10,14-tetramethyl-2-(2'-methyl-1',3'-dioxolan-2'-yl)-6-(phenylsulfonyl)octadeca-9,13-dien-5-one 
• 127750-74-7 (2R,4S,5RS,6RS,8S,17RS,9E,13E)-17-<(tert-Butyl)dimethylsilyloxy>-4,8,10,14-tetramethyl-2-(2'-methyl-1',3'-dioxolan-2'-yl)-6-(phenylsulfonyl)octadeca-9,13-dien-5-yl Benzoate 
• 127750-75-8 (2R,4S,5RS,6RS,8S,17RS,9E,13E)-17-<(tert-Butyl)dimethylsilyloxy>-4,8,10,14-tetramethyl-2-(2'-methyl-1',3'-dioxolan-2'-yl)-6-(phenylsulfonyl)<5-³H>octadeca-9,13-dien-5-yl Benzoate 
• 127779-23-1 (5E,9E)-(S)-13-Benzenesulfonyl-5,9,11-trimethyl-trideca-5,9-dien-2-ol 
• 121587-32-4 ((4E,8E)-(S)-12-Benzenesulfonyl-1,4,8,10-tetramethyl-dodeca-4,8-dienyloxy)-tert-butyl-dimethyl-silane 
• 127750-73-6 (9E,13E)-(2R,4S,8S)-6-Benzenesulfonyl-17-(tert-butyl-dimethyl-silanyloxy)-4,8,10,14-tetramethyl-2-(2-methyl-[1,3]dioxolan-2-yl)-octadeca-9,13-dien-5-one 
• 121587-31-3 (4E,8E)-(S)-12-Benzenesulfonyl-4,8,10-trimethyl-dodeca-4,8-dienoic acid methyl ester 
• 121587-31-3 (10S,4E,8E)-Methyl 4,8,10-Trimethyl-12-(phenylsulfonyl)dodeca-4,8-dienoate 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF A PUTATIVE TRIENE INTERMEDIATE IN MONENSIN BIOSYNTHESIS, ACTIVATED AS A CAPRYLCYSTEAMINE THIOL ESTER.

The total synthesis is reported, from a pool of optically pure starting materials, of a tritium labelled form of a putative intermediate in monensin biosynthesis, in which the terminal carboxyl group is activated as a caprylcysteamine thiol ester.