127827-01-4Relevant academic research and scientific papers
Iminyl Radicals: Part I. Generation and Intramolecular Capture by an Olefin.
Boivin, Jean,Fouquet, Eric,Zard, Samir Z.
, p. 1745 - 1756 (2007/10/02)
Slow addition of tributylstannane to sulphenylimines 2 give the corresponding Δ1-pyrrolenines 5 by an intramolecular addition of the intermediate iminyl radical, a process which can be easily coupled to an intermolecular addition to an electrophilic olefin.
CYCLISATION OF IMINE RADICALS DERIVED FROM SULPHENYLIMINES: A SIMPLE ACCESS TO Δ1-PYRROLINES
Boivin, Jean,Fouquet, Eric,Zard, Samir Z.
, p. 85 - 88 (2007/10/02)
Treatment of various sulphenylimines containing a γ,δ-double bond with tri-n-butylstannane affords the corresponding pyrroline derivatives in good yield.
