127839-25-2Relevant articles and documents
Synthesis of Allenes by -Sigmatropic Rearrangement of Prop-2-yn-1-yl Oxonium Ylides formed in Rhodium(II) Carboxylate catalysed Reactions of Diazo Compounds
Doyle, Michael P.,Bagheri, Vahid,Claxton, E. Elizabeth
, p. 46 - 48 (2007/10/02)
High oxophilicity of metal carbenes formed in rhodium(II) perfluorobutyrate catalysed decomposition of diazocarbonyl compounds allows selective ylide generation from methyl prop-2-yn-1-yl ethers with resulting allene production through the -sigmatropic rearrangement.