127844-86-4

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 132929-09-0 (4S,5R)-4-Benzyloxymethyl-2-phenyl-5-((Z)-propenyl)-[1,3]dioxane 
• 127854-76-6 (Z)-(2S,3R)-1-Benzyloxy-3-benzyloxymethyl-4-hexen-2-ol 
• 78469-85-9 (2S,3S)-4-benzyloxy-2,3-epoxy-1-butanol 
• 132929-09-0 (4S,5R)-4-Benzyloxymethyl-2-phenyl-5-((E)-propenyl)-[1,3]dioxane 
• 78513-07-2 (-)-(2S,3R)-2,3-epoxy-4-(benzyloxy)-1-butanol 
• 132121-57-4 (Z)-(2R,3S)-4-Benzyloxy-2-(1-propenyl)-1,3-butanediol 
• 127854-76-6 (E)-(2S,3R)-1-Benzyloxy-3-benzyloxymethyl-4-hexen-2-ol 

Downstream Products

• 127844-87-5 (4S,5S)-4,5-Bis-benzyloxymethyl-2-methyl-tetrahydro-furan-3-ol 
• 120567-30-8 1-((3R,4S)-3,4-Bis-benzyloxymethyl-oxetan-2-yl)-ethanol 
• 120567-31-9 (2S,3R,4S)-3,4-Bis(benzyloxymethyl)-2-acetyloxetane 
• 127844-87-5 (2R,3R,4S,5S)-4,5-Bis-benzyloxymethyl-2-methyl-tetrahydro-furan-3-ol 
• 120567-30-8 (S)-1-((2S,3R,4S)-3,4-Bis-benzyloxymethyl-oxetan-2-yl)-ethanol 
• 120567-37-5 (2R,3R,4S)-3,4-Bis(benzyloxymethyl)-2-acetyloxetane 
• 127844-87-5 (2S,3S,4S,5S)-4,5-Bis-benzyloxymethyl-2-methyl-tetrahydro-furan-3-ol 
• 120567-30-8 (R)-1-((2R,3R,4S)-3,4-Bis-benzyloxymethyl-oxetan-2-yl)-ethanol 
• 120567-29-5 1-O-Acetyl-2-deoxy-2-hydroxymethyl-D-erythrooxtanose dibenzoate 
• 120567-31-9 (3R,4S)-3,4-Bis(benzyloxymethyl)-2-acetyloxetane 

Relevant academic research and scientific papers

An improved, practical synthesis of the derivatives of 1-O-acetyl-2-deoxy-2-hydroxymethyl-D-erythrooxetanose, a key sugar moiety for the synthesis of oxetanosyl-N-glycoside

Intramolecular cyclization of the cis-epoxy-alcohol (6) with KOH in aq.DMSO provided predominantly the oxetane compound (7), which on oxidation followed by Baeyer-Villiger reaction gave 1-O-acetyl-D-erythrooxetanoses.

A FACILE AND PRACTICAL SYNTHESIS OF THE DERIVATIVES OF 1-O-ACETYL-2-DEOXY-2-HYDROXYMETHYL-D-ERYTHROOXETANOSE, A KEY SUGAR MOIETY FOR THE SYNTHESIS OF OXETANOSYL-N-GLYCOSIDE

Intramolecular cyclization of the epoxy-alcohol (6) with KOH in aq.DMSO gave predominantly the oxetane compound (7), which could be transformed into some 1-O-acetyl-D-oxetanoses.