127844-89-7Relevant academic research and scientific papers
An expedient route to acylated glucosyl halides with a free 2-OH group
Lichtenthaler, Frieder W.,Koehler, Bernd
, p. 77 - 86 (2007/10/02)
The carbonyl group of 3,4,6-tri-O-benzoyl-α-D-arabino-hexosyl-2-ulose bromide (8), readily accessible from the hydroxyglycal ester, can be reduced by cyanoborohydride without affecting the anomeric bromine; exclusive axial attack of the hydride affords th
Various glycosyl donors with a ketone or oxime function next to the anomeric centre: Facile preparation and evaluation of their selectivities in glycosidations
Lichtenthaler,Klares,Lergenmuller,Schwidetzky
, p. 179 - 184 (2007/10/02)
An efficient one-pot procedure is described for the conversion of a variety of hydroxyglycal esters to their 2-oxoglycosyl bromides which simply comprises of brief treatment with nN-bromosuccinimide/methanol at ambient temperature. Exhibiting comparably l
Acylated 2-oxoglycosyl bromides: Exploration of their reaction potential
Lichtenthaler, Frieder W.,Schwidetzky, Sabine,Nakamura, Katsumi
, p. 71 - 74 (2007/10/02)
Acylated glycos-2-ulosyl bromides give a variety of useful ensuing reactions, preparatively most relevant being their smooth α- and β-selective glycosidation, their reduction to glucosyl bromides with a free 2-OH, and their C-homologation to higher-carbon
