127870-76-2Relevant academic research and scientific papers
Synthesis of diaza paracyclophanetetraene and diaza paracyclophanehexaene
Bauchat, Patrick,Foucaud, Andre
, p. 6337 - 6338 (1989)
The diazabicyclooctane-catalyzed reaction of terephthalaldehyde with methyl acrylate gave the diester 2 or the monoester 4.The diester 2, acetylated and treated with ammonia gave a diaza paracyclophane 6 and the macrobicycle 7.The diester 8, obtaine
Star-like polyionic heterogeneous nanocatalyst as a highly active catalyst for promotion of Baylis-Hillman reaction in [bmim]Cl
Valizadeh, Hassan,Shomali, Ashkan,Noorshargh, Saeideh
, p. 2169 - 2177 (2015/10/19)
The use of star-like polyionic Lewis base heterogeneous nanocatalyst for the Baylis-Hillman reaction of benzyl- and methylacrylates with aryl aldehydes has been investigated. The corresponding Baylis-Hillman adducts are obtained in good to high yields in
Synthesis and Structural Features of New Orthocyclophanes, Cyclophanes and Corresponding Macrobicyclic Cryptophanes.
Bauchat, Patrick,Bras, Nathalie Le,Rigal, Luc,Foucaud, Andre
, p. 7815 - 7826 (2007/10/02)
The Baylis-Hillman reaction of dialdehydes with methyl acrylate, followed by acetylation of the resulting diols gave diacetates 3, 14, 16 and 20.Treated with ammonia, these diacetates afforded new cyclophanes and the corresponding macrobicyclic cryptophan
Selective mono and biscondensations of dialdehydes with methylacrylate
Fort,Berthe,Caubere
, p. 1265 - 1275 (2007/10/02)
DABCO-catalysed mono and biscondensations of dialdehydes with methylacrylate can be easily performed with good to high selectivity under mild conditions.
