127889-65-0Relevant academic research and scientific papers
Synthesis and Structural Features of New Orthocyclophanes, Cyclophanes and Corresponding Macrobicyclic Cryptophanes.
Bauchat, Patrick,Bras, Nathalie Le,Rigal, Luc,Foucaud, Andre
, p. 7815 - 7826 (2007/10/02)
The Baylis-Hillman reaction of dialdehydes with methyl acrylate, followed by acetylation of the resulting diols gave diacetates 3, 14, 16 and 20.Treated with ammonia, these diacetates afforded new cyclophanes and the corresponding macrobicyclic cryptophan
Synthesis of diaza paracyclophanetetraene and diaza paracyclophanehexaene
Bauchat, Patrick,Foucaud, Andre
, p. 6337 - 6338 (2007/10/02)
The diazabicyclooctane-catalyzed reaction of terephthalaldehyde with methyl acrylate gave the diester 2 or the monoester 4.The diester 2, acetylated and treated with ammonia gave a diaza paracyclophane 6 and the macrobicycle 7.The diester 8, obtaine
