1279009-83-4

Upstream product

• 1384863-66-4 C₁₂H₁₉N₃O₄ 
• 1277172-66-3 (1R,2R,3R,4S,5S)-5-(acetoxy)-3-(benzyloxy)-4-(tert-butoxycarbonylamino)cyclohexane-1,2-diol 
• 1277172-65-2 (3S,4S,5S)-5-(acetoxy)-3-(benzyloxy)-4-(tert-butoxycarbonylamino)cyclohex-1-ene 
• 1277172-63-0 (4S,5S,6S)-6-(benzyloxy)-5-(tert-butoxycarbonylamino)octa-1,7-dien-4-yl acetate 

Relevant academic research and scientific papers

Regioselectivity in the ring opening of epoxides for the synthesis of aminocyclitols from D-(-)-quinic acid

Efficient syntheses of four aminocyclitols are reported. Each synthesis is accomplished in eight steps starting from D-(-)-quinic acid. The key step involves a highly regioselective ring opening of epoxides by sodium azide.

Synthesis of aminocyclitols and trihydroxylated indolizidinone from a D-mannitol-derived common building block

The synthesis of 4-amino-4-deoxy-muco-quercitol (22), 4-amino-4-deoxy-(-)- vibo-quercitol (27) and also a trihydroxylated indolizidinone 38 from D-mannitol is described using ring-closing metathesis and diastereoselective dihydroxylation as the key steps.