1279129-39-3Relevant academic research and scientific papers
Tetrasubstituted olefins through the stereoselective catalytic intermolecular conjugate addition of simple alkenes to α,β- unsaturated carbonyl compounds
Kwon, Ki-Hyeok,Lee, Do W.,Yi, Chae S.
supporting information; experimental part, p. 1692 - 1695 (2011/04/15)
Branching out: The cationic ruthenium-hydride complex [Ru]+ was found to be a highly effective catalyst precursor for the conjugate addition of unactivated olefins to α,β-unsaturated carbonyl compounds to yield tetrasubstituted olefins. A kinetic analysis provides support for the mechanism involving a regioselective olefin insertion and rapid alkene isomerization steps.
