127966-37-4

Basic information

• Product Name: [Pd((4-phenyl-3-ido)(6-phenyl)pyrimidin)(μ-Cl)]2
• CAS NO: 127966-37-4
• Molecular Weight: 746.299
• Mol File: 127966-37-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd((4-phenyl-3-ido)(6-phenyl)pyrimidin)(μ-Cl)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd((4-phenyl-3-ido)(6-phenyl)pyrimidin)(μ-Cl)]2(127966-37-4)
• EPA Substance Registry System: [Pd((4-phenyl-3-ido)(6-phenyl)pyrimidin)(μ-Cl)]2(127966-37-4)

Safety Data

• Hazardous Substances Data: 127966-37-4(Hazardous Substances Data)

Upstream product

• 3977-48-8 4,6-diphenylpyrimidine 

Downstream Products

• 1167421-86-4 [(4-phenyl-3-ido)(6-phenyl)pyrimidin](ethylenediamine)palladium(II) perchlorate 

Relevant articles and documents

Cyclopalladated ethylenediamine complexes on the basis of 4-phenylpyrimidine and 4,6-diphenylpyrimidine

Mono-and binuclear cyclopalladated complexes [Pd(ppm)En]ClO4, [Pd(Hdphpm)En]ClO4, and [(PdEn)2(μ-dphpm)]ClO 4 (ppm- is the deprotonated form of 4-phenylpyridine, Hdphpm- and dphpm2- are the mono-and bisdeprotonated forms of 4,6-diphenylpyrimidine, En is 1,2-diaminoethane) were prepared and characterized by means of 1H NMR and electronic absorption and emission spectroscopy, and cyclic voltammetry. It was shown that cyclopalladation leads to a bathochromic shift of intraligand absorption and phosphorescence bands, appearance of new absorption band associated with metal-to-ligand charge transfer, and an anodic potential shift of the ligand-centered electroreduction Hppm ≈ H2dphpm + ≈ [Pd(Hdphpm)En]+ 2(μ-dphpm)]2+.