1279693-17-2

Basic information

• Product Name: (E)-1-fluoro-2-(1-nitroprop-1-en-2-yl)benzene
• Synonyms: (E)-1-fluoro-2-(1-nitroprop-1-en-2-yl)benzene
• CAS NO: 1279693-17-2
• Molecular Weight: 181.166
• Mol File: 1279693-17-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1-fluoro-2-(1-nitroprop-1-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-fluoro-2-(1-nitroprop-1-en-2-yl)benzene(1279693-17-2)
• EPA Substance Registry System: (E)-1-fluoro-2-(1-nitroprop-1-en-2-yl)benzene(1279693-17-2)

Safety Data

• Hazardous Substances Data: 1279693-17-2(Hazardous Substances Data)

Upstream product

• 445-27-2 2'-Fluoroacetophenone 
• 344-73-0 1-fluoro-2-(prop-1-en-2-yl)benzene 

Relevant articles and documents

1,3-Difunctionalization of β-alkyl nitroalkenes via combination of Lewis base catalysis and radical oxidation

Upon treatment with a Lewis base catalyst, β-alkyl-substituted nitroalkenes could be readily converted into allylic nitro compounds. Examples of either C-1 or C-3 functionalization methods have been reported through nitro-elimination, giving alkene products. In this work, successful 1,3-difunctionalization was achieved through a synergetic Lewis base catalysis and TBHP radical oxidation, giving vinylic alkoxyamines in good to excellent yields. This work further extended the general synthetic application of β-alkyl nitroalkenes.

Rh-catalyzed highly enantioselective hydrogenation of nitroalkenes under basic conditions

Go catalytic! A highly enantioselective hydrogenation of β,β-disubstituted nitroalkenes and isomeric mixtures of nitroalkenes by using a Rh/DuanPhos catalytic system under basic conditions has furnished a convenient approach to β-chiral nitroalkanes, whic