1280219-89-7Relevant academic research and scientific papers
Gold-catalyzed cascade friedel-crafts/furan-yne cyclization/heteroenyne metathesis for the highly efficient construction of phenanthrene derivatives
Chen, Yifeng,Li, Guijie,Liu, Yuanhong
, p. 392 - 400 (2011/04/22)
A rapid access to highly substituted phenanthrenyl ketones through gold-catalyzed cyclization of 1,6-diyn-4-en-3-ols with furans has been developed. Gold catalysts are effective to catalyze three cascade processes involving Friedel-Crafts/furan-yne cyclization/heteroenyne metathesis through C-O bond and alkyne activation. This method offers several advantages such as high selectivities and easily accessible starting materials.
