128041-98-5

Basic information

• Product Name: ((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-methanol
• CAS NO: 128041-98-5
• Molecular Weight: 578.703
• Mol File: 128041-98-5.mol

Chemical Properties

• CAS DataBase Reference: ((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: ((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-methanol(128041-98-5)
• EPA Substance Registry System: ((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-methanol(128041-98-5)

Safety Data

• Hazardous Substances Data: 128041-98-5(Hazardous Substances Data)

Upstream product

• 114406-21-2 [(2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methyl-hexahydro-pyrano[2,3-b]pyran-3-yl]-methanol 
• 107-30-2 chloromethyl methyl ether 

Downstream Products

• 128041-99-6 2,3,5-tri-O-benzyl-4,6-dideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2-C-methyl-8-aldehydo-D-talo-L-threo-1,1':1',7-bipyranoside-ocitol 
• 128041-95-2 2,3,5,9-tetra-O-benzyl-4,6,8-trideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-glycero-L-galacto-L-altro-1,1':1':7-bipyranoside-undecitol 
• 128041-97-4 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol 
• 128041-94-1 (2S,3R,4S)-3-Benzyloxy-2-hydroxy-2-methyl-4-((2R,3R,4S,4aS,5S,6S,8aS)-4,5,6-tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-pentanal 
• 128062-06-6 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,10,11-pentadeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol 
• 128041-93-0 (3R,4R,5S)-4-Benzyloxy-3-methyl-5-((2R,3R,4S,4aS,5S,6S,8aS)-4,5,6-tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-hex-1-en-3-ol 
• 128041-92-9 2,3,5,9-tetra-O-benzyl-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8-di-C-methyl-L-galacto-L-altro-10-ulo-1',1-bipyranoside-decitol 
• 115072-44-1 2,3,5,9-tetra-O-benzyl-4,6,8-10,11-pentadeoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-L-galacto-L-altro-1,1':1',7-bipyranoside-undecitol 
• 128042-03-5 (R)-2-((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-propionaldehyde 
• 128042-00-2 2,3,5-tri-O-benzyl-4,6,9-trideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2-C-methyl-8-ulo-D-talo-L-threo-1,1':1',7-bipyranoside-nonitol 
• 128042-01-3 2,3,5-tri-O-benzyl-4,6,8,9-tetradeoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8-di-C-methyl-D-talo-L-threo-8-eno-1,1':1',7-bipyranoside-nonitol 

Relevant articles and documents

Support Studies for Formulating the Nine Contiguous Chiral Centres of Streptovaricin A Ansa Chain

The tripyranoside (1b), which had been previously prepared as a key intermediate for the synthesis of the streptovaricin A ansa chain, lacks synthons for the C-24-CO2Me and C-28 tertiary alcohol of the antibiotic .The 'upper' acetal ring of (1b) has been cleaved selectively, an exocyclic methylene is develeoped at C-6, and a hydroboration sequence has been used to install an axial hydroxymethyl group as the synthon for the CO2Me group.In order to provide a self-consistent means of structure verification, both epimers of the C-10 tertiary alcohol have been prepared by utilizing empirically determined strategies for acyclic stereoselection.