128041-97-4

Basic information

• Product Name: 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol
• CAS NO: 128041-97-4
• Molecular Weight: 831.841
• Mol File: 128041-97-4.mol

Chemical Properties

• CAS DataBase Reference: 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol(CAS DataBase Reference)
• NIST Chemistry Reference: 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol(128041-97-4)
• EPA Substance Registry System: 7,10-anhydro-2,3,5-tri-O-benzyl-11-bromo-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-D-(or L-)glycero-L-talo-L-altro-1',1-pyranose-undecitol(128041-97-4)

Safety Data

• Hazardous Substances Data: 128041-97-4(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 128042-02-4 2,3,5-tri-O-benzyl-4,6,8-trideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8-di-C-methyl-D-altro-L-lyxo-1,1':1',7-bipyranoside-nonitol 
• 128041-89-4 (2R,4R,4aR,5S,6S,8aS)-4,5,6-Tris-benzyloxy-2-[(1R,2R)-2-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-1-methyl-propyl]-6-methyl-tetrahydro-pyrano[2,3-b]pyran-3-one 
• 114406-17-6 2,3,5,9-tetra-O-benzyl-4,6,8-trideoxy-4-C-(1'-formyl)-(1'S)-2,8-di-C-methyl-10-O-t-butyldimethylsilyl-L-lyxo-L-altro-6-eno-1',1-bipyranoside-decitol 
• 123505-98-6 (2R,3S,4R,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-2-[(1R,2R)-2-benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-1-methyl-propyl]-6-methyl-hexahydro-pyrano[2,3-b]pyran-3-ol 
• 128041-91-8 (2R,3S)-2-Benzyloxy-3-((2R,3R,4S,4aS,5S,6S,8aS)-4,5,6-tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-butyraldehyde 
• 114406-21-2 [(2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-6-methyl-hexahydro-pyrano[2,3-b]pyran-3-yl]-methanol 
• 128041-92-9 2,3,5,9-tetra-O-benzyl-4,6,8,11-tetradeoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8-di-C-methyl-L-galacto-L-altro-10-ulo-1',1-bipyranoside-decitol 
• 128041-90-7 2,3,5,9-tetra-O-benzyl-4,6,8-trideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8-di-C-methyl-L-galacto-L-altro-1',1-bipyranoside-decitol 
• 115072-44-1 2,3,5,9-tetra-O-benzyl-4,6,8-10,11-pentadeoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2,8,10-tri-C-methyl-L-galacto-L-altro-1,1':1',7-bipyranoside-undecitol 
• 128062-05-5 2,3,5,9-tetra-O-benzyl-4,8-dideoxy-4-C-(1'-formyl)-(1'S)-2,8-di-C-methyl-L-talo-L-altro-1',1-bipyranoside-decitol 
• 128042-03-5 (R)-2-((2S,3R,4S,4aS,5S,6S,8aS)-4,5,6-Tris-benzyloxy-3-methoxymethoxymethyl-6-methyl-hexahydro-pyrano[2,3-b]pyran-2-yl)-propionaldehyde 
• 128042-00-2 2,3,5-tri-O-benzyl-4,6,9-trideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2-C-methyl-8-ulo-D-talo-L-threo-1,1':1',7-bipyranoside-nonitol 
• 128041-99-6 2,3,5-tri-O-benzyl-4,6-dideoxy-4-C-(1'-formyl)-(1'S)-6-C-(1-methoxymethoxymethyl)-2-C-methyl-8-aldehydo-D-talo-L-threo-1,1':1',7-bipyranoside-ocitol 

Downstream Products

• 129163-51-5 (2S,3S,4R)-3-Benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-2-[(S)-benzyloxy-((S)-4-methyl-2-oxo-[1,3]dioxolan-4-yl)-methyl]-5-methoxymethoxy-pentanal 
• 129163-50-4 (S)-4-[(1S,2S,3R,4R)-1,3-Bis-benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-5-methoxymethoxy-2-vinyl-pentyl]-4-methyl-[1,3]dioxolan-2-one 
• 123506-07-0 (S)-4-[(1S,2S,3S,4R)-1,3-Bis-benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-2-hydroxymethyl-5-methoxymethoxy-pentyl]-4-methyl-[1,3]dioxolan-2-one 
• 123506-08-1 (S)-4-[(1S,2S,3S,4R)-1,3-Bis-benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-2-iodomethyl-5-methoxymethoxy-pentyl]-4-methyl-[1,3]dioxolan-2-one 
• 123506-12-7 (3R,4R,5R,6S)-4-Benzyloxy-6-[(1R,2R,3S,4S)-2,4-bis-benzyloxy-1-methoxymethoxymethyl-3-methyl-4-((S)-2,2,4-trimethyl-[1,3]dioxolan-4-yl)-butyl]-3-hydroxy-3,5-dimethyl-tetrahydro-pyran-2-one 
• 129163-52-6 (S)-4-[(1S,2S,3R,4R)-1,3-Bis-benzyloxy-4-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-5-methoxymethoxy-2-methyl-pentyl]-4-methyl-[1,3]dioxolan-2-one 
• 129163-53-7 (3R,4R,5R,6S)-4-Benzyloxy-6-[(1R,2R,3S,4S)-2,4-bis-benzyloxy-1-methoxymethoxymethyl-3-methyl-4-((S)-2,2,4-trimethyl-[1,3]dioxolan-4-yl)-butyl]-3,5-dimethyl-tetrahydro-pyran-2,3-diol 
• 129163-48-0 {(2S,3R,4S,5S)-3-Benzyloxy-4-[(1S,2R)-1-benzyloxy-2-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-3-methoxymethoxy-propyl]-5-iodomethyl-2-methyl-tetrahydro-furan-2-yl}-methanol 
• 129163-49-1 (2S,3S,4S,5R,6R)-3,5-Bis-benzyloxy-6-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-7-methoxymethoxy-2-methyl-4-vinyl-heptane-1,2-diol 
• 123506-09-2 Tri-O-benzyl-1,2-O-carbonyl-4,6,8,10,11-pentadeoxy-6-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-L-altro-L-galacto-10-eno-undecitol 
• 123506-11-6 tri-O-benzyl-4,6,8,11,12-pentadeoxy-1,2-O-isopropylidene-6-C-(1''-methoxymethoxymethyl)-2,4,8,10-tetra-C-methyl-D-glycero-L-allo-D-gulo-11-eno-dodecitol 
• 123506-10-5 (3R,4S,5R,6S,7R,8S,9S)-3,7,9-Tris-benzyloxy-6-methoxymethoxymethyl-2,4,8-trimethyl-9-((S)-2,2,4-trimethyl-[1,3]dioxolan-4-yl)-non-1-en-5-ol 
• 129189-24-8 (2S,3S,4S)-3,4-Bis-benzyloxy-2-[(1S,2R)-1-benzyloxy-2-((2R,3S,4R,5S)-4-benzyloxy-5-bromomethyl-3,5-dimethyl-tetrahydro-furan-2-yl)-3-methoxymethoxy-propyl]-5-hydroxy-4-methyl-pentanoic acid methoxy-methyl-amide 

Relevant articles and documents

Support Studies for Formulating the Nine Contiguous Chiral Centres of Streptovaricin A Ansa Chain

The tripyranoside (1b), which had been previously prepared as a key intermediate for the synthesis of the streptovaricin A ansa chain, lacks synthons for the C-24-CO2Me and C-28 tertiary alcohol of the antibiotic .The 'upper' acetal ring of (1b) has been cleaved selectively, an exocyclic methylene is develeoped at C-6, and a hydroboration sequence has been used to install an axial hydroxymethyl group as the synthon for the CO2Me group.In order to provide a self-consistent means of structure verification, both epimers of the C-10 tertiary alcohol have been prepared by utilizing empirically determined strategies for acyclic stereoselection.