1280575-75-8Relevant academic research and scientific papers
Ortho-hydroxy bioactive schiff base compounds: Design, comprehensive characterization, photophysical properties and elucidation of antimicrobial and mutagenic potentials
N?bras Qader Qader, Israa,Obal?, ?hsan,?smet U?an, Halil,Uysal, Ahmet,Y?lmaz Obal?, Asl?han,Kul, Mustafa
, (2021/11/30)
Preparation and comprehensive characterization of three Schiff base ligands; with trimethoxy substitution (1E,1′E)-N,N'-(naphthalene-1,5-diyl)bis(1-(3,4,5-trimethoxyphenyl)methanimine, 1, with ortho-hydroxy substitution 6,6′-((1E,1′E)-(naphthalene-1,5-diy
Polymorphism driven optical properties of an anil dye
Safin, Damir A.,Robeyns, Koen,Babashkina, Maria G.,Filinchuk, Yaroslav,Rotaru, Aurelian,Jureschi, Catalin,Mitoraj, Mariusz P.,Hooper, James,Brela, Mateusz,Garcia, Yann
, p. 7249 - 7259 (2016/10/07)
Red crystals of N,N′-bis(3-methoxysalicylidene)-1,5-diiminonaphthalene were obtained after Schiff base condensation in ethanol. Recrystallization from acetone afforded yellow crystals, a process which is reversible and reproducible. Single crystal X-ray diffraction evidences two polymorphs differing in their space group and dihedral angle between aromatic moieties. DFT periodic calculations further confirmed the existence of two minima on the potential energy surface corresponding to red and yellow crystals. The red polymorph irreversibly (monotropically) transforms at 165-190 °C into the yellow one with a 3% increase of the unit cell volume, as shown by X-ray powder diffraction and periodic DFT calculations. Both polymorphs are thermochromic but only the red one displays photochromism upon irradiation at λ = 365 nm, which is reversible and exhibits a relatively slow thermal relaxation. A temperature induced cis/trans-keto equilibrium is for the first time identified for an N-salicylidene aniline derivative. Static DFT molecular and periodic calculations as well as ab initio Born-Oppenheimer dynamics simulations were performed to characterize the stability of both polymorphs and to determine the relative populations of the enol/cis-keto/trans-keto isomers at various temperatures.
Synthesis and characterization of the transition metal complexes: Their alcohol oxidation and electrochemical properties
Tuemer, Mehmet
experimental part, p. 211 - 223 (2011/04/25)
Five Schiff base ligands, HA1, HA2, H 2L1-H2L3, and their Co(II), Mn(III) and Ru(III) complexes, have been synthesized and characterized by analytical, spectroscopic, conductance, magnetic
