128070-53-1

Basic information

• Product Name: 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-oxazolidine-2,4-dione
• Synonyms: 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-oxazolidine-2,4-dione
• CAS NO: 128070-53-1
• Molecular Weight: 253.373
• Mol File: 128070-53-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-oxazolidine-2,4-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-oxazolidine-2,4-dione(128070-53-1)
• EPA Substance Registry System: 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-oxazolidine-2,4-dione(128070-53-1)

Safety Data

• Hazardous Substances Data: 128070-53-1(Hazardous Substances Data)

Upstream product

• 2346-26-1 2,4-oxazolidinedione 
• 13224-83-4 6-trimethylsilyl-5-hexyn-2-ol 

Downstream Products

• 128070-55-3 3-(1-Methyl-5-trimethylsilanyl-pent-4-ynyl)-4-phenylsulfanyl-oxazolidin-2-one 

Relevant articles and documents

Diastereoselective synthesis of 2,6-disubstituted 3-hydroxypiperidine, 2-(α-hydroxyalkyl)-3-hydroxypiperidine and 2-(α-hydroxyalkyl)-3-hydroxypyrrolidine derivatives

Reduction of 5-substituted 5,8a-trans-oxazolopyridin-8-ones (7a,b), obtained by an application of α-acylamino radical cyclization at the initial stage, with NaBH4 and K-Selectride was found to proceed with complete stereocontrol in all cases.Reduction of 1-substituted 1,8a-trans-oxazolopyridin-8-one (7c) and pyrrolidine analogue (10) with NaBH4 and K-Selectride was also found to proceed with high diastereoselectivity.