1280737-75-8Relevant academic research and scientific papers
Sulfur-directed olefin oxidations: Observation of divergent reaction mechanisms in the palladium-mediated acetoxylation of unsaturated thioacetals
Mann, Sam E.,Aliev, Abil E.,Tizzard, Graham J.,Sheppard, Tom D.
scheme or table, p. 1772 - 1775 (2011/06/22)
The Pd-mediated oxidation of unsaturated thioacetals gives either allyl or vinyl esters, depending on the substrate structure. We report the characterization of a range of sulfur-stabilized palladium intermediates via a combined computational and experime
