128080-53-5

Upstream product

• 721918-02-1 4-oxo-3-phenyl-3,4-dihydro-1H-naphthalene-2,2-dicarboxylic acid 
• 104958-17-0 diethyl 2-phenyl-1,2,3,4-tetrahydronapthalene-1-one-3,3-dicarboxylate 

Downstream Products

• 128080-51-3 C₂₀H₁₉NO₄ 
• 128080-51-3 C₂₀H₁₉NO₄ 
• 127845-15-2 (Z)-methyl 3-phenyl-4-hydroxyimino-1,2,3,4-tetrahydronaphthalene-2-carboxylate 
• 127845-15-2 (E)-methyl 3-phenyl-4-hydroxyimino-1,2,3,4-tetrahydronaphthalene-2-carboxylate 
• 128080-54-6 methyl 3,3,4,4,5,5-hexahydro-3-phenylbenzoazepin-1-one-4-carboxylate 
• 127845-14-1 methyl trans-(2R^*,3R^*)-3-phenyl-1,2,3,4-tetrahydronaphthalen-4-one-2-carboxylate 

Relevant academic research and scientific papers

BENZOPHENANTHRIDINES. X. INVESTIGATION OF THE RODIONOV-SUVOROV SCHEME. REDUCTIVE ACETYLATION OF THE OXIMES OF 3-ETHOXYCARBONYL-SUBSTITUTED 2-PHENYLTETRAL-1-ONES WITH STANNOUS CHLORIDE IN ACETIC ANHYDRIDE

When treated with anhydrous stannous chloride in acetic anhydride, the oximes of benzyl phenyl ketone and 3-alkoxycarbonyl- and 3,3-dialkoxycarbonyl-2-phenyltetralones give a mixture of enamides and enimides.The direction of the reaction does not depend on the configuration of the oxime.It takes place in a more well-defined manner with the derivatives of 2-phenyltetralones used in the synthesis of benzophenanthridines by the Rodionov-Suvorov method.