128121-04-0Relevant articles and documents
SYNTHESIS OF THE NATURALLY OCCURING CYTOKININ 2'-DEOXYZEATIN RIBOSIDE
Napoli, Lorenzo de,Evidente, Antonio,Piccialli, Gennaro,Santacroce, Ciro,Vellone, Rita
, p. 701 - 703 (1990)
2'-Deoxyzeatin riboside, previously isolated together with other three cytokinins from culture filtrates of the pathogenic bacterium Pseudomonas amygdali, has been synthesized by reaction of 6-chloro-9-(2-dexy-β-D-ribofuranosyl)purine with (E)-4-amino-2-methyl-but-2-en-1-ol.The identity of the synthetic and the naturally occuring cytokinin has been established.
Total synthesis of the alkaloids martinelline and martinellic acid via a hetero Diels-Alder multicomponent coupling reaction
Powell, David A.,Batey, Robert A.
, p. 2913 - 2916 (2007/10/03)
(formula presented) A concise synthesis of the guanidine alkaloids, (±)-martinelline and (±)-martinellic acid, using a protic acid catalyzed 2:1 hetero Diels-Alder coupling reaction between N-Cbz 2-pyrroline and methyl 4-aminobenzoate, is described. Protic acid catalysis, rather than Lewis acid catalysis, was necessary to achieve the desired sense of diastereocontrol in the coupling reaction.