128141-13-9Relevant academic research and scientific papers
Reaction of singlet oxygen with alkenylidenecyclopropanes: Implication for a peroxyallyl intermediate
Akasaka, Takeshi,Misawa, Yoshihisa,Ando, Wataru
, p. 1173 - 1176 (2007/10/02)
Photosensitized oxygenation of adamantenylidenecyciopropanes (1) gave either the corresponding oxetanones (2a-c) or the cyclic ketones (4 and 5) depending on the substituent on the cyclopropane ring in addition to adamantanone. The results are rationalized in terms of initial formation of a perepoxide followed by that of a peroxyallyl intermediate.
