99337-53-8Relevant academic research and scientific papers
Mild Generation of Adamantylidenevinylidene (an Alkenylidenecarbene) from 2-Bromo-2-(trimethylsilylethynyl)adamantane and (2-Bromo-2-trimethylsilylvinylidene)adamantane
Eguchi, Shoji,Ikemoto, Tomoyuki,Kobayakawa, Yasuyuki,Sasaki, Tadashi
, p. 958 - 959 (1985)
Adamantylidenevinylidene, a new alkenylidenecarbene, was successfully generated by fluoride-initiated elimination of trimethylsilyl and bromo groups from 2-bromo-2-(trimethylsilylethynyl)adamantane and (2-bromo-2-trimethylsilylvinylidene)adamantane.
Synthesis of Novel Carbo- and Hetero-polycycles. Part 8. An Efficient and Convenient Synthesis of Adamantylidenevinylidenecyclopropane Derivatives
Eguchi, Shoji,Arasaki, Motohiro
, p. 1047 - 1050 (2007/10/02)
Crown ether catalysed dehydrochlorination of 2-chloro-2-ethynyladamantane (3) with ButOK provided a convenient and efficient method for the synthesis of adamantylidenevinylidene (4).In the presence of olefins (5a-o), compound (4) afforded the c
