128155-67-9

Upstream product

• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 128155-61-3 2-(4-Methoxyphenyl)-2-thiomethoxy-1,3-dithiane 
• 24588-72-5 2-(4-methoxyphenyl)-1,3-dithiane 

Relevant academic research and scientific papers

Trithioorthoesters and Tetrathioorthocarbonates as RC(3+) and C(4+) Synthons. Nickel-Catalyzed Alkylative Olefination of Trithioorthoesters and Tetrathioorthocarbonates

NiCl2(PPh3)2-catalyzed alkylative olefinations of trithioorthoesters and tetrathioorthocarbonates give the corresponding substituted alkenes.Aliphatic C-S bonds in these substrates can be activated in the nickel-catalyzed cross coupling reaction leading to carbon-carbon bond formation.This reaction can be considered as using trithiorthoesters and tetrathioorthocarbonate as R3C(3+) and C(4+) synthons. - Keywords: Trithioorthoesters, Tetrathioorthocarbonate, Nickel-Catalyzed Alkylative Olefination, Synthons of RC(3+) and C(4+)

Nickel-catalysed Alkylative Alkenation of Orthothioesters with Grignard Reagents; a Convenient Procedure for introducing the Isopropenyl Group. Synthesis of Substituted 1,3-(Bis-trimethylsilyl)propenes

Nickel-catalysed coupling of orthothioesters with MeMgI furnishes a general method for introducing the isopropenyl group; the application of this reaction to the synthesis of 1,3-(bis-trimethylsilyl)propenes is presented.