128162-83-4

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 70831-49-1 (4S,5S)-4-hydroxymethyl-2,2-dimethyl-5-tosyloxymethyl-1,3-dioxolane 

Downstream Products

• 133337-03-8 (4S,5S)-4-Benzyl-5-but-3-enyl-2,2-dimethyl-[1,3]dioxolane 
• 177959-35-2 Toluene-4-sulfonic acid (2S,3S)-4-(4-benzyloxy-phenyl)-2,3-dihydroxy-butyl ester 
• 1327254-74-9 (S)-N-((3S,11bS)-9,11-bis(benzyloxy)-4-oxo-2,3,4,6,7,11b-hexahydro-1H-pyrido[2,1-a]isoquinolin-3-yl)-16-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)-14-((triethylsilyl)oxy)hexadecanamide 
• 1327254-69-2 benzyl (R,Z)-16-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)-14-((triethylsilyl)oxy)hexadec-11-enoate 
• 122881-05-4 ((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)methyl-4-methylbenzenesulfonate 
• 177959-34-1 (2S,3S)-4-(4'-benzyloxyphenyl)-2,3-O-isopropylidenedioxy-1-p-toluenesulfonyloxybutane 
• 130967-59-8 Toluene-4-sulfonic acid (4S,5S)-5-[4-(tert-butyl-dimethyl-silanyloxy)-but-2-ynyl]-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester 

Relevant academic research and scientific papers

A Novel Carbon-Carbon Bond-Forming Reaction of Triflates with Copper(I)-Catalyzed Grignard reagents. A New Concise and Enantiospecific Synthesis of (+)-exo-Brevicomin, (5R,6S)-(-)-6-Acetoxy-5-hexadecanolide, and L-Factor

We describe here a full accound of a highly concise and enantiospecific synthesis of (+)-exo-brevicomin (7), (5R,6S)-(-)-6-acetoxy-5-hexadecanolide (11), and L-factor (16) originating from D- or L-tartrates as chiral sources.The synthesis employs an effic

Ytterbium(III) trifluoromethanesulfonate catalyzed high pressure reaction of epoxides with indole. An enantioselective synthesis of (+)-diolmycin A2

Epoxide opening reactions with indole are efficiently accelerated under high pressure conditions in the presence of a catalytic amount of ytterbium(III) trifluoromethanesulfonate to afford tryptophol derivatives. The procedure is successfully applied for an enantioselective synthesis of (+)-diolmycin A2.

Synthesis of Lateral Root-Inducing Compounds Using an Efficient Coupling Reaction of Chiral Triflates

Lateral root-inducing compounds, isolated from the bacterium Erwinia quercina, have been synthesized by using a coupling reaction of chiral triflates derived from L- or D-tartrates and their biological activities examined.