128163-76-8Relevant academic research and scientific papers
CHIRALE INDUKTION BEI DER PHOTOCHEMISCHEN UMLAGERUNG VON 3,6-HEXANOOXEPIN-4,5-DICARBONSAEUREESTERN
Tochtermann, Werner,Schloesser, Ulrike,Popp, Brigitta,Peters, Eva-Maria,Peters, Karl,Schnering, Hans Georg von
, p. 6855 - 6858 (1989)
Irradiation of an aqueous suspension of the crystalline diester 1d affords the (+)-(3aS, 6R, 8aR)-methanohydroazulene 2d in 45percent yield with 83percent de.The absolute configurations were established via the X-ray structural analysis of the dimenthylester (+)-2b and chemical transformations.
