128176-20-5Relevant academic research and scientific papers
Electrocatalytic reactions: anion radical cyclobutanation reactions and electrogenerated base reactions
Felton, Greg A.N.
, p. 884 - 887 (2008/09/17)
Intermolecular anion radical [2+2] cyclobutanation reactions have been observed between vinyl sulfones and vinyl/propenyl ketones. The products are novel and formed electrocatalytically, although yields are at best modest (11-45%). Competing mechanisms are discussed. Additionally, the electrochemical reduction of vinyl alkyl sulfones in acetonitrile leads to near quantitative formation of cyanomethylation product cyano-sulfones. The single step approach has electrocatalytic factors in excess of thirty.
Electrochemical reduction of activated olefins in deuteriated solvents. II. A regioselective deuteriation catalytic process from α,β-ethylenic aryl sulfones
Delaunay, Jacques,Ghanimi, Ahmed,Diederichs, Sophie,Simonet, Jacques
, p. 165 - 171 (2007/10/03)
The title compounds were electrochemically reduced in aprotic dimethyl sulfoxide-d6, acetonitrile-d3 or organic solvents containing heavy water. When a catalytic amount of charge passed through the cell, α-deuteriation of olefins occ
THE CYCLODIMERIZATION OF ARYL VINYL SULPHONES: A FACILE AND SPECIFIC REACTION WHEN ACTIVATED BY CATHODIC ELECTRON TRANSFER
Delaunay, Jacques,Mabon, Gilles,Orliac, Armelle,Simonet, Jacques
, p. 667 - 668 (2007/10/02)
Aryl vinyl sulphones, when "reduced" under well defined experimental conditions, do not lead to cleavage products or to hydrodimers but to cyclodimers, namely trans bis-1,2-(aryl sulphonyl)-cyclobutanes.
