128207-26-1

Upstream product

• 653-34-9 2,3,4,5,6-pentafluorostyrene 
• 624-38-4 para-diiodobenzene 
• 623-27-8 terephthalaldehyde, 
• 7651-11-8 (pentafluorophenyl)diazomethane 
• 653-37-2 perfluorobenzaldehyde 
• 908838-30-2 2,3,4,5,6-pentafluorobenzaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone 

Downstream Products

• 128207-27-2 1-[2,5-Bis-(2-pentafluorophenyl-ethyl)-phenyl]-ethanone 
• 128207-25-0 C₂₂H₁₂F₁₀ 

Relevant academic research and scientific papers

Fluorinated distyrylbenzene chromophores: effect of fluorine regiochemistry on molecular properties and solid-state organization

A series of fluorinated distyrylbenzene (DSB) derivatives were synthesized and studied in order to probe the effect of fluorine substitution on molecular properties and on the arrangement of molecules in the solid state. Reaction of 1,4-diiodobenzene with

Rh2(OAc)4-catalyzed formation of trans-alkenes from the reaction of aldehydes with perfluorophenyl diazomethane through tellurium ylide

Rh2(OAc)4 can catalyze the formation of perfluorophenyl-containing trans-epoxides from the reactions of perfluorophenyl diazomethane with activated aryl aldehydes through sulfur ylide intermediate. In contrast, under the same reactio

Transition-Metal-Catalyzed Formation of trans Alkenes via Coupling of Aldehydes

(Equation presented) Rh2(OAc)4 catalyzed the formation of exclusively trans fluorinated alkenes from aldehydes and pentafluorobenzaldehyde tosylhydrazone salts, which were readily prepared from pentafluorobenzaldehyde using the Bamfo

Phenyl-perfluorophenyl stacking interactions: Topochemical [2+2] photodimerization and photopolymerization of olefinic compounds

The face-to-face stacking interaction between phenyl and perfluorophenyl groups is emerging as a common noncovalent interaction. To explore the generality of this supramolecular synthon, the solid-state packing structure and reactivity of several monoolefins and diolefins substituted with phenyl and perfluorophenyl groups was investigated. Of the seven crystalline or cocrystalline materials investigated, six were found to undergo a photochemically induced [2+2] reaction in the solid state. By determining the stereochemistry of the photoproduct and/or X-ray structural analysis of the olefinic precursors, the stacked interaction between phenyl and perfluorophenyl groups in the photoactive crystals were revealed.