128224-91-9Relevant articles and documents
New approach to oximes through reduction of nitro compounds enabled by visible light photoredox catalysis
Cai, Shunyou,Zhang, Shaolong,Zhao, Yaohong,Wang, David Zhigang
supporting information, p. 2660 - 2663 (2013/07/11)
A range of nitro compounds are smoothly reduced to their corresponding oximes under the synergistic effects of visible light irradiation, the Ru(bpy)3Cl2 photocatalyst, Hünig's base, Mg(ClO 4)2 activation, and MeCN solvent. This remarkably mild and environmentally benign protocol, when orchestrated with classical Beckmann rearrangement, enables such high-value industrial feedstock as caprolactam to be readily accessed from simple precursor nitrocyclohexane.
Indium-mediated reduction of β-nitrostyrenes to oximes in aqueous media
Yadav,Subba Reddy,Srinivas,Ramalingam
, p. 1447 - 1449 (2007/10/03)
β-Nitrostyrenes are selectively reduced to the corresponding oximes in high yields by indium metal in aqueous methanol under neutral reaction conditions.