128291-13-4

Basic information

• Product Name: (2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopentanone
• CAS NO: 128291-13-4
• Molecular Weight: 434.694
• Mol File: 128291-13-4.mol

Chemical Properties

• CAS DataBase Reference: (2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopentanone(128291-13-4)
• EPA Substance Registry System: (2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopentanone(128291-13-4)

Safety Data

• Hazardous Substances Data: 128291-13-4(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 128291-07-6 (E)-4-[3-(tert-Butyl-dimethyl-silanyloxy)-1,1-dimethyl-propyl]-hepta-2,6-dienoic acid methyl ester 
• 128291-20-3 2-Allyl-3,3-dimethyl-pentanedioic acid dimethyl ester 
• 128291-06-5 2-[3-(tert-Butyl-dimethyl-silanyloxy)-1,1-dimethyl-propyl]-pent-4-en-1-ol 
• 128291-08-7 (E)-4-(1,1-Dimethyl-3-oxo-propyl)-hepta-2,6-dienoic acid methyl ester 
• 128291-11-2 (2R,3R)-3-Allyl-2-(2-hydroxy-ethyl)-4,4-dimethyl-cyclopentanol 
• 128291-05-4 2-Allyl-3,3-dimethyl-pentane-1,5-diol 
• 19184-67-9 methyl 3,3-dimethylglutarate 
• 128291-12-3 (2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopentanol 

Downstream Products

• 128291-17-8 {(1S,5R,8R)-8-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6,6-dimethyl-2-oxo-bicyclo[3.2.1]oct-1-yl}-acetonitrile 
• 128291-15-6 [(2S,3S)-2-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-3-(3-oxo-propyl)-cyclopent-(E)-ylidene]-acetonitrile 
• 128291-16-7 {(1S,5R,8R)-8-[2-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-2-hydroxy-6,6-dimethyl-bicyclo[3.2.1]oct-1-yl}-acetonitrile 
• 128291-14-5 [(2S,3S)-3-Allyl-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4,4-dimethyl-cyclopent-(E)-ylidene]-acetonitrile 

Relevant articles and documents

Electroreductive cyclization reactions. Stereoselection, creation of quaternary centers in bicyclic frameworks, and a formal total synthesis of quadrone

The electroreductive cyclization reaction has been successfully applied to an efficient formal total synthesis of quadrone (1). Two of the four rings were created electrochemically, a third via a novel oxidativedecarboxylation and cyclization onto a remote nitrile functional group (22a24).