128308-23-6

Upstream product

• 100-51-6 benzyl alcohol 
• 128308-19-0 (3aR,5S,6S,6aR)-5-((S)-2-Benzyloxy-1-chloro-ethyl)-2,2,6-trimethyl-tetrahydro-furo[2,3-d][1,3]dioxole 
• 114144-67-1 6-O-benzyl-3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-allofuranose 
• 128308-20-3 (2S,3S,4R)-1-Benzyloxy-2-chloro-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-pentan-3-ol 
• 128308-21-4 [(4R,5S,6S)-6-((S)-2-Benzyloxy-1-chloro-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-methanol 
• 74924-27-9 methyl (S)-3-benzyloxy-2-methylpropanoate 
• 106357-28-2 (2S,3S,4S)-1-benzyloxy-2,4-dimethyl-hex-5-en-3-ol 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 128308-24-7 {(1R,2S)-3-Benzyloxy-1-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methyl-propoxy}-tert-butyl-dimethyl-silane 
• 15681-48-8 lithium dimethylcuprate 
• 128308-22-5 (R)-4-[(S)-1-((2S,3R)-3-Benzyloxymethyl-oxiranyl)-ethyl]-2,2-dimethyl-[1,3]dioxolane 
• 77-76-9 2,2-dimethoxy-propane 

Downstream Products

• 128308-27-0 3-[(1S,4S,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-1-methoxy-4-methyl-heptyl]-phenol 
• 128308-25-8 (4S,5R,6S)-1-(3-Benzyloxy-phenyl)-5-(tert-butyl-dimethyl-silanyloxy)-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methyl-heptan-1-one 
• 128308-26-9 {(1R,2S,5S)-5-(3-Benzyloxy-phenyl)-1-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-5-methoxy-2-methyl-pentyloxy}-tert-butyl-dimethyl-silane 
• 128308-24-7 {(1R,2S)-3-Benzyloxy-1-[(S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-ethyl]-2-methyl-propoxy}-tert-butyl-dimethyl-silane 

Relevant academic research and scientific papers

Improved Synthesis of the C8-C23 Segment of Aplysiatoxins via Asymmetric Dihydroxylation of the Chiral Homoallylic Alcohol

Important intermediate 2 of the segment (3) possessing four sequential asymmetric centers (C9-C12) of aplysiatoxins was synthesized via dihydroxylation of 5 in only 7 steps from methyl (S)-3-hydroxy-2-methylpropionate.Another promising compound (10a) was

SYNTHETIC STUDY ON APLYSIATOXINS, HIGHLY INFLAMMATORY AGENTS AND TUMOR PROMOTERS. SYNTHESIS OF THE THREE OPTICALLY ACTIVE SEGMENTS

The main segments in debromoaplysiatoxin and related aplysiatoxins have been efficiently synthesized from D-glucose and L- and D-tartaric acids.