208172-68-3Relevant academic research and scientific papers
Improved Synthesis of the C8-C23 Segment of Aplysiatoxins via Asymmetric Dihydroxylation of the Chiral Homoallylic Alcohol
Toshima, Hiroaki,Ichihara, Akitami
, p. 599 - 602 (1998)
Important intermediate 2 of the segment (3) possessing four sequential asymmetric centers (C9-C12) of aplysiatoxins was synthesized via dihydroxylation of 5 in only 7 steps from methyl (S)-3-hydroxy-2-methylpropionate.Another promising compound (10a) was
