1283160-97-3Relevant articles and documents
Nickel-catalyzed reductive cleavage of aryl-oxygen bonds in alkoxy- and pivaloxyarenes using hydrosilanes as a mild reducing agent
Tobisu, Mamoru,Yamakawa, Ken,Shimasaki, Toshiaki,Chatani, Naoto
supporting information; experimental part, p. 2946 - 2948 (2011/04/24)
A nickel-catalyzed reductive deoxygenation of aryl alkyl ethers and aryl pivalates has been developed. Hydrosilanes serve as a mild reducing agent. The present protocol allows the use of a pivalate group as a robust and traceless steering group in arene functionalization reactions. The Royal Society of Chemistry.