128329-22-6

Upstream product

• 115869-43-7 (tert-butyldiphenylsilanyloxy)acetaldehyde 
• 1415934-59-6 (2S,3S)-1-((S)-4-benzyl-2-thioxothiazolidin-3-yl)-4-(tert-butyldiphenylsilyloxy)-3-hydroxy-2-methylbutan-1-one 
• 106820-50-2 2,3-dideoxy-3-C-methyl-5-O-tert-butyldiphenylsilyl-D-threo-pentono-1,4-lactone 
• 87770-83-0 (Z)-4-((tert-butyldiphenylsilyl)oxy)but-2-en-1-ol 
• 917-54-4 methyllithium 
• 117901-01-6 ((2S,3R)-3-(((tert-butyldiphenylsilyl)oxy)methyl)oxiran-2-yl)methanol 

Downstream Products

• 128329-23-7 (2S,3R)-1-(tert-Butyl-diphenyl-silanyloxy)-3-methyl-4-trityloxy-butan-2-ol 
• 1415934-60-9 tert-butyl(((4S,5R)-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl)methoxy)diphenylsilane 
• 1331882-90-6 (2R,3S)-4-(tert-butyldiphenylsilyloxy)-3-(4-methoxybenzyloxy)-2-methylbutan-1-ol 
• 1415934-61-0 (4S,5R,6S)-7-(tert-butyldiphenylsilyloxy)-6-(4-methoxybenzyloxy)-5-methylhept-1-en-4-ol 
• 1415934-62-1 (4R,5R,6S)-7-(tert-butyldiphenylsilyloxy)-6-(4-methoxybenzyloxy)-5-methylhept-1-en-4-ol 
• 1331882-39-3 C₆₀H₁₀₂O₁₃Si₂ 
• 1331883-18-1 C₂₆H₃₅IO₄ 
• 1331883-08-9 C₃₅H₄₄O₆S 
• 1331883-02-3 C₂₅H₃₄O₅ 
• 1331882-99-5 C₂₅H₃₆O₅ 
• 1331882-96-2 C₄₁H₅₄O₅Si 
• 1331882-93-9 C₂₉H₃₆O₄Si 
• 128329-31-7 2,2-Dimethyl-propionic acid (4S,5R,6R)-2,2,5-trimethyl-6-((R)-1-methyl-2-trityloxy-ethyl)-[1,3]dioxan-4-ylmethyl ester 
• 128329-31-7 2,2-Dimethyl-propionic acid (4R,5R,6R)-2,2,5-trimethyl-6-((R)-1-methyl-2-trityloxy-ethyl)-[1,3]dioxan-4-ylmethyl ester 

Relevant academic research and scientific papers

Iridium-catalyzed allylation of chiral β-stereogenic alcohols: Bypassing discrete formation of epimerizable aldehydes

The cyclometalated π-allyliridium 3,4-dinitro-C,O-benzoate complex modified by (R)- or (S)-Cl,MeO-BIPHEP promotes the transfer hydrogenative coupling of allyl acetate to β-stereogenic alcohols with good to excellent levels of catalyst-directed diastereose

γ-allyl Phosphinoyl Phenyl Sulfone (GAPPS): A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3-Dienes

A three-operation conjunctive strategy is available for the synthesis of EE, EZ, and ET dienes. This protocol employs a sequential Wadsworth?Emmons reaction using a GAPPS reagent followed by alkylation of an allylic sulfone anion, and finally ligand-mediated, palladium-catalyzed desulfonylation. Copyright