501084-29-3Relevant academic research and scientific papers
γ-allyl Phosphinoyl Phenyl Sulfone (GAPPS): A Conjunctive Reagent for the Synthesis of EE, EZ, and ET 1,3-Dienes
Li, Xiaojin,Lantrip, Douglas,Fuchs, Philip L.
, p. 14262 - 14263 (2007/10/03)
A three-operation conjunctive strategy is available for the synthesis of EE, EZ, and ET dienes. This protocol employs a sequential Wadsworth?Emmons reaction using a GAPPS reagent followed by alkylation of an allylic sulfone anion, and finally ligand-mediated, palladium-catalyzed desulfonylation. Copyright
Synthesis and conformational analysis of meso-ter(1,3-dioxan-4-yls)
Hoffmann, Reinhard W.,Mas, Gemma,Brandl, Trixi
, p. 3455 - 3464 (2007/10/03)
A convergent synthesis of the meso-ter(1,3-dioxanyls) 8-11 has been achieved, starting from two enantiomeric building blocks in each case. The stereogenic centres in the central linkage region were set up by stereocontrolled aldol additions. Structure ass
