128358-33-8

Basic information

• Product Name: <3aR-<1(4S^*,5R^*),3aα,6α,7aβ>>-1-<(4,5-dihydro-4-methyl-3-phenyl-5-isoxazolyl)carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide
• CAS NO: 128358-33-8
• Molecular Weight: 402.514
• Mol File: 128358-33-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <3aR-<1(4S^*,5R^*),3aα,6α,7aβ>>-1-<(4,5-dihydro-4-methyl-3-phenyl-5-isoxazolyl)carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: <3aR-<1(4S^*,5R^*),3aα,6α,7aβ>>-1-<(4,5-dihydro-4-methyl-3-phenyl-5-isoxazolyl)carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(128358-33-8)
• EPA Substance Registry System: <3aR-<1(4S^*,5R^*),3aα,6α,7aβ>>-1-<(4,5-dihydro-4-methyl-3-phenyl-5-isoxazolyl)carbonyl>hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole 2,2-dioxide(128358-33-8)

Safety Data

• Hazardous Substances Data: 128358-33-8(Hazardous Substances Data)

Upstream product

• 94594-81-7 (E)-1-((3aR,6S,7aS)-8,8-dimethyl-2,2-dioxidotetrahydro-3H-3a,6-methanobenzo[c]isothiazol-1(4H)-yl)but-2-en-1-one 
• 698-16-8 benzohydroximoyl chloride 
• 108448-77-7 (+)-camphorsultam 

Relevant articles and documents

On the Scope of Asymmetric Nitrile Oxide Cycloadditions with Oppolzer's Chiral Sultam. Total Syntheses of (+)-Hepialone, (-)-(1R,3R,5S)-1,3-Dimethyl-2,9-dioxabicyclooctane

Cycloadditions of nitrile oxides with acryloyl derivatives of Oppolzer's chiral sultam produce stereoisomeric Δ2-isoxazolines in ratios of about 90/10 at 25 deg C.The major diastereomers can be isolated in pure form in 70-88percent yield.Synthe