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94594-81-7

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  • 2-Buten-1-one,1-[(3aR,6S,7aS)-tetrahydro-8,8-dimethyl-2,2-dioxido-3H-3a,6-methano-2,1-benzisothiazol-1(4H)-yl]-,(2E)-

    Cas No: 94594-81-7

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94594-81-7 Usage

General Description

(S)-(+)-(2-buteno-1,4-oyl)-2,10-camphorsultam, also known as CAM-B, is a chiral building block commonly used in organic synthesis. It is derived from camphor and possesses a unique conformation due to its rigid structure. CAM-B is a versatile compound and can be used in various transformations, including asymmetric catalysis and synthesis of chiral compounds. It has the potential to influence the stereochemistry of reactions and is an important intermediate for the production of pharmaceuticals, agrochemicals, and materials. CAM-B has gained attention in the field of asymmetric synthesis due to its ability to induce high enantioselectivity in reactions. Overall, CAM-B is a valuable chemical for the development of asymmetric synthesis strategies and the production of chiral compounds with high optical purity.

Check Digit Verification of cas no

The CAS Registry Mumber 94594-81-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,4,5,9 and 4 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 94594-81:
(7*9)+(6*4)+(5*5)+(4*9)+(3*4)+(2*8)+(1*1)=177
177 % 10 = 7
So 94594-81-7 is a valid CAS Registry Number.
InChI:InChI=1/C14H21NO3S/c1-4-5-12(16)15-11-8-10-6-7-14(11,13(10,2)3)9-19(15,17)18/h4-5,10-11H,6-9H2,1-3H3/b5-4+/t10-,11-,14-/m0/s1

94594-81-7 Well-known Company Product Price

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  • Aldrich

  • (534986)  (S)-(+)-(2-Butenoyl)-2,10-camphorsultam  97%

  • 94594-81-7

  • 534986-500MG

  • 909.09CNY

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94594-81-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name (N-Crotonyl)-(2S)-bornane-10,2-sultam

1.2 Other means of identification

Product number -
Other names ((E)-2-butenoyl)-(7R)-10,10-dimethyl-5-thia-4-azatricyclo((5.2.1.0)3,7)decane-5,5-dioxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:94594-81-7 SDS

94594-81-7Downstream Products

94594-81-7Relevant articles and documents

MACROCYCLIC SPIROETHERS AS MCL-1 INHIBITORS

-

Paragraph 0535; 0536, (2020/07/31)

Provided are compounds represented by Formula (I-A) and the pharmaceutically acceptable salts and solvates thereof, wherein R8, R9a, R9b, R9c, R9d, X, Y, Z, Z1, W, and (aa) are as defined as set forth in the specification. Provided are also compounds of Formula (I-A) for use to treat a condition or disorder responsive to Mcl-1 inhibition such as cancer.

Progress toward the total synthesis of callipeltin A (I): Asymmetric synthesis of (3S,4R)-3,4-dimethylglutamine

Liang, Bo,Carroll, Patrick J.,Joullie, Madeleine M.

, p. 4157 - 4160 (2007/10/03)

(equation presented) During the total synthesis of the novel cyclic depsipeptide callipeltin A (1), the unit (3S,4R)-3,4-dimethylglutamine, was successfully synthesized by asymmetric Michael addition and subsequent electrophilic azidation. The key feature of this approach is the generation of three adjacent stereogenic centers using the same camphorsultam chiral auxiliary.

A practical method for N-acylation of bornane-2,10-sultam and 2-oxazolidinones

Thom,Kocienski

, p. 582 - 586 (2007/10/02)

The N-trimethylsilyl derivatives of (+)-bornane-2,10-sultam (10,10-dimethyl-5-thia-4-azatricyclo[5.2.1.03,7]decane 5,5-dioxide) and (R)-4-benzyl-2-oxazolidinone and 4-methyl-5-phenyl-2-oxazolidinone react with acid chlorides in refluxing benzen

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