1283595-57-2Relevant academic research and scientific papers
Copper(II)-catalyzed dehydrogenative cross-coupling between two azoles
Qin, Xurong,Feng, Boya,Dong, Jiaxing,Li, Xiaoyu,Xue, Ying,Lan, Jingbo,You, Jingsong
supporting information, p. 7677 - 7683 (2012/11/06)
The copper(II)-catalyzed dehydrogenative coupling between two different azoles for the preparation of unsymmetrical biazoles has been developed. The current catalytic system can effectively control the chemoselectivity for heterocoupling over homocoupling.
Palladium-catalyzed dehydrogenative cross-couplings of benzazoles with azoles
Han, Wei,Mayer, Peter,Ofial, Armin R.
supporting information; experimental part, p. 2178 - 2182 (2011/04/17)
Different enough: Palladium-catalyzed cross-couplings of benzazoles with imidazoles, oxazoles, and thiazoles furnish unsymmetrical 2,2′- bisheteroaryls in high yield (see scheme). These oxidative Ci-C bond formations use the selective cleavage of the Ci-H bond at C2 in the two coupling partners and are robust enough to be conducted under normal air atmosphere.
