128367-83-9Relevant academic research and scientific papers
ARYL-COUPLING VIA "AXIALLY PROSTEREOGENIC" LACTONES: FIRST TOTAL SYNTHESIS OF (+)-ANCISTROCLADISINE AND (OPTIONALLY) ITS ATROPISOMER
Bringmann, Gerhard,Reuscher, Helmut
, p. 5249 - 5252 (2007/10/02)
The first total synthesis of the liana alkaloid ancistrocladisine (1a) and of its novel atropisomer 1b is reported.The required mixed aryl coupling is brought about, regiospecifically, by prefixation of the two molecular moieties by an ester-type auxiliar
